These guys have a great idea. I think it would prove even better with more refinement. They can start by cutting out the needless blather and focus more on the subjects at hand. The opening music cue is cute, but doesn't really set an acccurate tone for what the listener is about to hear. After that it seems to take these guys a while to get at the heart of the podcast's topic.
In my opinion, it's clear these guys know what they're doing and they appear to be knowledgable about their content. A little more focus, discipline and editing would put the necessary polish on what looks like a potentially 1st rate podcast.